Can I read Short communication: Thermal stability of the diazohydroborate [1‐N~2~B~10~H~9~]^−^: degradation to [B~20~H~18~]^2−^ anion on EtoBox?

Short communication: Thermal stability of the diazohydroborate [1‐N~2~B~10~H~9~]^−^: degradation to [B~20~H~18~]^2−^ anion by Daoud Naoufal; Bernard Bonnetot; Henri Mongeot is a Chemistry article available to read on EtoBox.

What is Short communication: Thermal stability of the diazohydroborate [1‐N~2~B~10~H~9~]^−^: degradation to [B~20~H~18~]^2−^ anion about?

## Abstract The thermal stability of the monodiazohydroborate NMe~4~[1‐N~2~B~10~H~9~] was studied by thermogravimetric analysis. Under two different atmospheres (air and argon), the thermal decomposition starts at a temperature between 140 and 160 °C. The decomposition residue obtained was separated on a silica gel column. ^11^B NMR, IR and electrospray mass spectroscopy analyses of the different fractions separated showed that the above decomposition produces (NMe~4~)~2~[B~20~H~18~] as major product (90%), along with smaller amounts of residual NMe~4~[1‐N~2~B~10~H~9~] (5%), (NMe~4~)~2~[B~12~H~12~] and boric acid. Copyright © 2003 John Wiley & Sons, Ltd.

Who reads Short communication: Thermal stability of the diazohydroborate [1‐N~2~B~10~H~9~]^−^: degradation to [B~20~H~18~]^2−^ anion?

Author

Daoud Naoufal; Bernard Bonnetot; Henri Mongeot

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0268-2605)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)