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Two Manganese(II) Complexes with a Bulky Fluorene‐Based Carboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties by Dr. Junjie Wang; Yunfeng Shi; Sujuan Li is a Chemistry article available to read on EtoBox.
What is Two Manganese(II) Complexes with a Bulky Fluorene‐Based Carboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties about?
## Abstract To explore the coordination possibilities of fluorene‐based ligands, two manganese(II) complexes with the ligand 9,9‐dibutyl‐9__H__‐fluorene‐2,7‐carboxylate (L) were synthesized and characterized: [Mn~2~(L)~2~(DMF)~3~]~∞~ (1) and [Mn~2~(L)~2~(DMF)]~∞~ (2). X‐ray single‐crystal diffraction analyses show that complex 1 has a two‐dimensional (2D) (4,4) structure, whereas complex 2 consits of a three‐dimensional (3D) (4,5)‐connected topology framework. The results indicate that the steric bulk of the fluorene ring in H~2~L plays an important role in the formations of 1 and 2. Additional pyridine‐based ligands govern the formation of the final frameworks of 2. Moreover, the luminescent properties of these complexes were briefly investigated.
Who reads Two Manganese(II) Complexes with a Bulky Fluorene‐Based Carboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Dr. Junjie Wang; Yunfeng Shi; Sujuan Li
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)
- Published
- 2011
- Language
- EN
- Field
- Chemistry (Physical Sciences)