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Effect of surface hydrophobization on the 1,5,9-cyclododecatriene epoxidation process with hydrogen peroxide on silanized Ti-SBA-15 catalyst by M. Kujbida; A. Wróblewska; G. Lewandowski; M. Bosacka; Zvi C. Koren; B. Michalkiewicz is a Engineering article available to read on EtoBox.

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This work presents the results of the epoxidation of 1,5,9-cyclododecatriene (CDT) to 1,2-epoxy-5,9-cyclododecadiene (ECDD) with hydrogen peroxide on unmodified and on silanized Ti-SBA-15 catalyst (named as Ti-SBA-15-TMS). Silanization was performed by a simple and quick method using hexamethyldisilazane. The catalyst was hydrophobic after modification, which was confirmed by FT-IR spectra in which the signals from the surface –OH groups and adsorbed water disappeared. The optimal solvent in terms of selectivity of transformation using H2O2 to ECDD was found to be 90 wt% acetone. From the comparison of the activities of Ti-SBA-15 and Ti-SBA-15-TMS catalysts, it is evident that silanization decreases the rate of the epoxidation reaction but increases the selectivities of transformation of CDT and H2O2 to ECDD. The low selectivity of the transformation of H2O2 to ECDD was a major concern during our studies on conducting this process on the Ti-MCM-41 catalyst. ECDD, due to the high degree of functionalization of the molecule, finds many applications both as a final product (perfume industry) and as an intermediate (epoxy resins and coatings), and can potentially be used as a raw mater

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Author

M. Kujbida; A. Wróblewska; G. Lewandowski; M. Bosacka; Zvi C. Koren; B. Michalkiewicz

Publisher

Elsevier BV

Published

2023

Language

EN

Field

Engineering (Physical Sciences)