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Can I read ChemInform Abstract: Stereodivergent Allylindation of Cyclopropenes. Remarkable Stereodirection and Acceleration by Neighboring Carboxyl and Hydroxyl Groups. on EtoBox?

ChemInform Abstract: Stereodivergent Allylindation of Cyclopropenes. Remarkable Stereodirection and Acceleration by Neighboring Carboxyl and Hydroxyl Groups. by S. ARAKI; H. NAKANO; K. SUBBURAJ; T. HIRASHITA; K. SHIBUTANI; H. YAMAMURA; M. KAWAI; Y. BUTSUGAN is a Chemistry article available to read on EtoBox.

What is ChemInform Abstract: Stereodivergent Allylindation of Cyclopropenes. Remarkable Stereodirection and Acceleration by Neighboring Carboxyl and Hydroxyl Groups. about?

The allylindation of cyclopropenes (I) is found to depend remarkably on the nature of the substituent at the α-carbon. Thus, a hydroxymethyl and carboxyl group direct to the cis products (III) based on intramolecular chelation, whereas acetoxymethyl and ester groups direct to trans products (IV) due to steric interaction with the incoming allylindium reagent (II). -(ARAKI, S.;

Who reads ChemInform Abstract: Stereodivergent Allylindation of Cyclopropenes. Remarkable Stereodirection and Acceleration by Neighboring Carboxyl and Hydroxyl Groups.?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
S. ARAKI; H. NAKANO; K. SUBBURAJ; T. HIRASHITA; K. SHIBUTANI; H. YAMAMURA; M. KAWAI; Y. BUTSUGAN
Publisher
John Wiley and Sons; Wiley (John Wiley & Sons); Wiley (ISSN 0931-7597)
Published
1998
Language
EN
Field
Chemistry (Physical Sciences)

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