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The nature of the metalmetal interaction in tetra-μ-carboxylatochromium(II) systems by C.David Garner; Ian H. Hillier; Martyn F. Guest; Jennifer C. Green; Anthony W. Coleman is a Physics and Astronomy article available to read on EtoBox.

What is The nature of the metalmetal interaction in tetra-μ-carboxylatochromium(II) systems about?

The results of an ab initio molec&r orbital caliculatio~ for Cr2(0$ZH)~,2H20 are presented. They indicate that the eight chromium d electrons, corresponding to a d4 configuration of each metal atom are accommodated in the metal-metal u, 6,6\* and o\* orbita!s to give no net bonding over the Cr-Cr separation of 2.362(l) A. The He(I) Photoelectron spectrum for Cr~(O$X!H& is described and interpreted with the aid of ASCF caiculations.

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Author

C.David Garner; Ian H. Hillier; Martyn F. Guest; Jennifer C. Green; Anthony W. Coleman

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

1976

Language

EN

Field

Physics and Astronomy (Physical Sciences)