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Influence of urea/glucose on the mixed micellization behavior of amitriptyline hydrochloride and 1-hexadecyl-3-methylimidazolium chloride (ionic liquid) mixtures: An experimental and theoretical investigation by Tahseen Kamal; Mohmad Shafi Sheikh; Malik Abdul Rub; Ashi Khalil is a Chemical Engineering article available to read on EtoBox.

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Mixtures of an antidepressant drug, amitriptyline hydrochloride (AMT), and ionic liquid, 1-hexadecyl-3-methylimidazolium chloride (HMICl), were investigated by tensiometry at a temperature of 298.15 K with diverse mole fraction (α 1) of HMICl to determine the association, surface, and thermodynamic properties. Fourier transform infrared (FTIR) and UV–visible spectroscopy were also used to estimate the interactions between AMT and HMICl. AMT can treat depression, anxiety, and other mental illnesses. Imidazolium-based surface-active ionic liquids are ideal for biomedical uses because of their unique physicochemical properties. The interaction between AMT and HMICl was also examined using non-aqueous solvent systems (500 mmol·kg−1 urea and 250 mmol·kg−1 glucose). The ideal cmc (cmc id) measured for the mixed system (AMT + HMICl) tensiometry was notably smaller than the critical micelle concentration (cmc). As a result, AMT and HMICl interact fairly well, and interaction also increased when the α 1 of HMICl increased. The cmc values for pure and mixed solutions in urea were higher than those in aqueous, while in glucose, they were lower. Hypothetical models, including those of Clint, M

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Author

Tahseen Kamal; Mohmad Shafi Sheikh; Malik Abdul Rub; Ashi Khalil

Publisher

Elsevier BV

Published

2023

Language

EN

Field

Chemical Engineering (Physical Sciences)