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Visible light degradation of ibuprofen using PANI coated WO3@TiO2 photocatalyst 1 1 Introduction 1 2 Experimental 2 2.1 Reagents 2 2.2 Fabrication of WO3 photocatalyst 2 2.3 Preparation of TiO2 nanorods 2 2.4 Preparation of WO3@TiO2 photocatalyst 3 2.5 Preparation of PANI/WO3@TiO2 photocatalyst 3 2.6 Photocatalyst characterization 3 2.7 Photocatalytic degradation evaluation studies 3 3 Results and discussion 3 3.1 FTIR analysis 3 3.2 Raman analysis 4 3.3 XRD analysis 5 3.4 BET analysis 5 3.5 Thermal analysis of the photocatalysts 5 3.6 Morphology characterization of the photocatalyst 5 3.7 Optical properties of the photocatalysts 6 3.8 Photoluminescence analysis 8 3.9 X-ray photoelectron spectroscopy 9 4 Application 9 4.1 Catalyst selection 9 4.2 Influence of solution pH on the degradation process 11 4.3 The influence of photocatalyst dosage 11 4.4 The influence of bicarbonate ions on the degradation process 11 4.5 The influence of persulfate ions on the degradation process 11 4.6 Kinetics studies 12 4.7 Photocatalytic mechanism 12 4.8 Reusability of PANI/ WO3@TiO2 13 4.9 Global discussion 13 5 Conclusion 13 Declaration of Competing Interest 13 Acknowledgments 13 References 13
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