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Can I read Cs~2~CO~3~-Promoted reaction of tertiary bromopropargylic alcohols and phenols in DMF: a novel approach to α-phenoxyketones on EtoBox?
Cs~2~CO~3~-Promoted reaction of tertiary bromopropargylic alcohols and phenols in DMF: a novel approach to α-phenoxyketones by Ol'ga G Volostnykh; Olesya A Shemyakina; Anton V Stepanov; Igor' A Ushakov is a Chemistry article available to read on EtoBox.
What is Cs~2~CO~3~-Promoted reaction of tertiary bromopropargylic alcohols and phenols in DMF: a novel approach to α-phenoxyketones about?
The reaction of bromopropargylic alcohols with phenols in the presence of Cs~2~CO~3~/DMF affords α-phenoxy-α’-hydroxyketones (1:1 adducts) and α,α-diphenoxyketones (1:2 adducts) in up to 92% and 24% yields, respectively. Both products are formed via ring opening of the same intermediates, 1,3-dioxolan-2-ones, generated in situ from bromopropargylic alcohols and Cs~2~CO~3~.
Who reads Cs~2~CO~3~-Promoted reaction of tertiary bromopropargylic alcohols and phenols in DMF: a novel approach to α-phenoxyketones?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Ol'ga G Volostnykh; Olesya A Shemyakina; Anton V Stepanov; Igor' A Ushakov
- Publisher
- Beilstein Institut
- Published
- 2022
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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