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Four New Compounds Constructed from Bis‐Antimony‐Capped Keggin Polyoxoanions {PMo~12~Sb~2~O~40~} and Different Coordination Fragments by Li-Na Xiao; Yu Peng; Yan Wang; Jia-Ning Xu; Zhong-Min Gao; Ya-Bing Liu; Da-Fang Zheng; Xiao-Bing Cui; Ji-Qing Xu is a Chemistry article available to read on EtoBox.
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## Abstract Four new heteropolyanions {[PMo~12~Sb~2~O~40~][Cu(Im)~2~]~2~}·Im (1), {[PMo~12~Sb~2~O~40~][(Cd(Phen)~2~)~2~Cl]} (2), [Cu(Phen)~2~]~2~[PMo~12~Sb~2~O~40~] (3) and [Cd(bpy)~4~(H~2~O)~2~][PMo~12~Sb~2~O~40~]·bpy·2H~2~O (4) (Im = imidazole, Phen = 1,10‐phenanthroline, bpy = 4,4′‐bipyridine) have been synthesized and characterized by IR, UV/Vis spectrophotometry, X‐ray photoelectron spectroscopy, powder XRD analyses and elemental analyses. Single‐crystal X‐ray diffraction analyses revealed that these four compounds represent examples of compounds based on the bis‐antimony‐capped Keggin polyoxoanion {PMo~12~Sb~2~O~40~} and different transition‐metal coordination complexes. Compound 1 exhibits a novel 1D chain structure, compound 2 is the first example of an extended structure constructed from polyoxoanions, transition‐metal coordination complexes and halide ions and compounds 3 and 4 are supramolecular structures constructed from {PMo~12~Sb~2~O~40~} polyoxoanions and different transition‐metal coordination fragments.
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- Author
- Li-Na Xiao; Yu Peng; Yan Wang; Jia-Ning Xu; Zhong-Min Gao; Ya-Bing Liu; Da-Fang Zheng; Xiao-Bing Cui; Ji-Qing Xu
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1434-1948)
- Published
- 2011
- Language
- EN
- Field
- Chemistry (Physical Sciences)