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This document discusses a novel organocatalytic method for the asymmetric synthesis of chiral selenylated δ-lactones through [4 + 2] annulation of selenyl vinyl ketones and enals, achieving yields of 54-88% with enantioselectivity of 90-99%. The study highlights the significance of selenylated dihydropyranones in pharmaceuticals and their potential enhanced properties due to selenyl functionalization. The authors optimized reaction conditions and explored the scope of various substrates, demonstrating the m

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ranadeep.chem.iitk

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EN