Can I read A kinetic study of the 1, 10-phenanthroline-catalysed iron(III) oxidation of epimeric aldo-, and D-, and L-ketohexoses on EtoBox?

A kinetic study of the 1, 10-phenanthroline-catalysed iron(III) oxidation of epimeric aldo-, and D-, and L-ketohexoses by Kolla N. Reddy; Mereddy K. R. Reddy; Kamatala C. Rajanna; Pondichery K. Saiprakash is a Chemistry article available to read on EtoBox.

What is A kinetic study of the 1, 10-phenanthroline-catalysed iron(III) oxidation of epimeric aldo-, and D-, and L-ketohexoses about?

Fe uI in H2SO~ medium does not oxidize sugars even at the reflux temperature, however, the reaction is catalysed by trace amounts of 1,10-phenanthroline (phen). A kinetic study shows that the oxidation rate increases as [phen] increases and exhibits a fractional order dependence upon [phen]. The orders with respect to [Fe Ill] and [carbohydrate] are unity. The oxidation rate decreases as [HSO~-] and [H2SO4] increase. A plausible mechanism is proposed involving participation of an [FeIII-phen] precursor and sugar in the rate-determining step,

Who reads A kinetic study of the 1, 10-phenanthroline-catalysed iron(III) oxidation of epimeric aldo-, and D-, and L-ketohexoses?

Author

Kolla N. Reddy; Mereddy K. R. Reddy; Kamatala C. Rajanna; Pondichery K. Saiprakash

Publisher

Springer; Springer-Verlag; Kluwer Academic Publishers; Springer Science and Business Media LLC; Society for Mining, Metallurgy and Exploration Inc. (ISSN 0340-4285)

Published

1996

Language

EN

Field

Chemistry (Physical Sciences)