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Chemo-hydro-mechanics in a reactive rock under cylindrical fluid pressurization 1 1 Introduction 1 2 Model Description 3 2.1 Reactive chemo-elasto-plasticity 3 2.2 Poromechanics considering chemical erosion 4 2.3 Transport in a reactive rock undergoing chemical degradation: carbonate formation as a representative example 5 3 Finite element implementation of the chemo-hydro-mechanical model 5 4 Model calibration with reactive-transport experiments on limestones 7 5 Simulation of cavity expansion subject to a combined action of internal pressurization and acid infiltration 7 5.1 Problem Statement 7 5.2 Rock response to chemical infiltration in terms of matrix behaviour and transport properties 9 5.3 Transition of matrix transport to advection–diffusion enabled by chemical erosion 10 5.4 Model sensitivity to the chemical boundary condition and micro-cracking intensity 12 6 Conclusion 15 CRediT authorship contribution statement 15 Declaration of Competing Interest 15 Data availability 15 Acknowledgements 15 Appendix: Derivation of the governing PDE for the transient problem of a deformation porous medium involving internal mass ... 15 References 16

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nonfiction