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A new type of A-homo-B-norcholestane derivatives by Alexander Kasal is a scholarly article available to read on EtoBox.

What is A new type of A-homo-B-norcholestane derivatives about?

5-Bromo-6β-chloro-5α-cholestan-3β-ol (I) undergoes solvolysis to yield products of Westphalen rearrangement one of them (XXIX) undergoing further rearrangement to the A-homo-B-nor-system V. The reaction course was established by the use of suitably labeled substrates. The structures of the products and positions of the labels were determined by chemical transformations and physicochemical methods (1H, 13C NMR spectra).

Author

Alexander Kasal

Published

1984

Language

EN