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Kinetics of the reactions of O3and OH radicals with furan and thiophene at 298 ± 2 K: REACTIONS OF O3AND OH RADICALS by Roger Atkinson; Sara M. Aschmann; William P. L. Carter is a Chemistry article available to read on EtoBox.

What is Kinetics of the reactions of O3and OH radicals with furan and thiophene at 298 ± 2 K: REACTIONS OF O3AND OH RADICALS about?

Rate constants for the reactions of 0 3 and OH radicals with furan and thiophene have been determined at 298 f 2 K. The rate constants obtained for the 0 3 reactions were (2.42 f 0.28) X 1O-lS cm3/molec.s for furan and <6 X cm3/molec-s for thiophene. The rate constants for the OH radical reactions, relative to a rate constant for the reaction of OH radicals with n-hexane of (5.70 f 0.09) X cm3/molec.s, were determined to be (4.01 f 0.30) X lo-" cm3/molec.s for furan and (9.58 f 0.38) X 10-l2 cm3/molec.s for thiophene. There are to date no reported rate constant data for the reactions of OH radicals with furan and thiophene or for the reaction of 0 3 with furan. The data are compared and discussed with respect to those for other alkenes, dialkenes, and heteroatom containing organics.

Who reads Kinetics of the reactions of O3and OH radicals with furan and thiophene at 298 ± 2 K: REACTIONS OF O3AND OH RADICALS?

Author

Roger Atkinson; Sara M. Aschmann; William P. L. Carter

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0538-8066)

Published

1983

Language

EN

Field

Chemistry (Physical Sciences)