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Synthesis of 1,3,5-tri- and 1,2,4,5-tetrasubstituted tin and mercury derivatives of benzene. Crystal structure of 1,3,5-tris(chloromercurio)benzene by Nicolette Rot; Frans J.J de Kanter; Friedrich Bickelhaupt; Wilberth J.J Smeets; Anthony L Spek is a Chemistry article available to read on EtoBox.
What is Synthesis of 1,3,5-tri- and 1,2,4,5-tetrasubstituted tin and mercury derivatives of benzene. Crystal structure of 1,3,5-tris(chloromercurio)benzene about?
The reaction of 1,3,5-tribromo-or 1,2,4,5-tetrabromobenzene with trimethylstannyl sodium in tetraglyme gave the corresponding polystannylated benzene derivatives 2 and 4, respectively, in high yield. They were converted with mercuric chloride to the corresponding tris-and tetrakis(chloromercurio)benzenes 5 and 6, respectively. The structure of 5 was confirmed by X-ray crystallography. Some spectral properties of the new compounds are discussed. The (partial) conversion of 2 to 1,3,5-trilithiobenzene (8) was also investigated.
Who reads Synthesis of 1,3,5-tri- and 1,2,4,5-tetrasubstituted tin and mercury derivatives of benzene. Crystal structure of 1,3,5-tris(chloromercurio)benzene?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Nicolette Rot; Frans J.J de Kanter; Friedrich Bickelhaupt; Wilberth J.J Smeets; Anthony L Spek
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 2000
- Language
- EN
- Field
- Chemistry (Physical Sciences)