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What is Palladium-Catalyzed B-Dialkenylation of o-Carboranes about?

This article presents a method for palladium-catalyzed regioselective B(3,5)-dialkenylation and B(4)-alkenylation of o-carboranes using a picolyl directing group with low catalyst loading. The study explores the influence of steric factors on substitution patterns and reaction efficiency, demonstrating high yields for various substrates. A plausible mechanism involving electrophilic palladation and alkyne insertion is proposed based on experimental results.

Author

asiakazmierczak460

Language

EN