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Supported transition metal complexes : I. Organic polymers as the slipport by K.G. Allum; R.D. Hancock; I.V. Howell; R.C. Pitkethly; P.J. Robinson is a Chemistry article available to read on EtoBox.

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Trivalent phosphorus ligand groups have been bonded to a wide range of organic polymers, including polyvinyl chloride, polystyrene, polybuiadiene and polyvinyl alcohol. The ligand-polymers complex with a variety of transition metal compounds, and the complexes obtained have been shown to catalyse hydrocarbon reactions such as the hydrogenation of 1-hesene and cyclohesene, the hydroformylation of 1-hexene and the cyclodimerisation of butadiene to 4-vinylcyclohexene and 1,5-cyclooctadiene. Macroreticular high surface area cross-linked polystyrene is the most satisfactory organic polymer support. Rhodium complexes of acetylacetone ligand-polymers have also been prepared.

Who reads Supported transition metal complexes : I. Organic polymers as the slipport?

Author

K.G. Allum; R.D. Hancock; I.V. Howell; R.C. Pitkethly; P.J. Robinson

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1975

Language

EN

Field

Chemistry (Physical Sciences)