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Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands by Sevim Hamamci; Veysel T. Yilmaz; William T.A. Harrison is a Chemistry article available to read on EtoBox.

What is Synthesis, IR spectra, thermal analysis and crystal structure of a one-dimensional coordination polymer containing both three- and four-coordinate silver(I) centers bridged by both saccharinate and N-(2-hydroxyethyl)piperazine ligands about?

A novel [Ag 2 (m-sac) 2 (m-hep) 2 ] n [sacZsaccharinate and hepZ{N-(2-hydroxyethyl)piperazine}] was synthesized and characterized. [Ag 2 (m-sac) 2 (m-hep) 2 ] n consists of dimeric [Ag 2 (m-sac) 2 ] units bridged by the hep ligands, resulting a one-dimensional coordination polymer. [Ag 2 (m-sac) 2 (m-hep) 2 ] n contains two different silver(I) centers with a Ag-Ag separation of 3.492(2) A ̊. One of the silver(I) ion is trigonal planar to the imino N and carbonyl O atoms of two sac ligands and one of the N atom of hep, while the other silver(I) ion is tetrahedrally coordinated by the N and carbonyl O atoms of two sac ligands and the N and O chelating hep ligand.

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Author

Sevim Hamamci; Veysel T. Yilmaz; William T.A. Harrison

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-2860)

Published

2005

Language

EN

Field

Chemistry (Physical Sciences)