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This document reports the first experimental observation of the high-energy cis conformer of acetic acid (cis-AA) produced in an argon matrix through vibrational excitation. The study demonstrates that cis-AA can interconvert to the more stable trans conformer via tunneling, even at low temperatures (8 K), with a significant effect of deuteration on the reaction rate. The findings contribute to understanding conformational properties in carboxylic acids and their implications for conformation-selective phot
- Author
- ingeniero.escorza
- Language
- EN