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Visible-Light-Driven Synthesis of Aryl Xanthates and Aryl Dithiocarbamates via an Electron Donor–Acceptor Complex by Mingjun Zhang; Beibei Wang; Yunpeng Cao; Yuxiu Liu; Ziwen Wang; Qingmin Wang is a Chemistry article available to read on EtoBox.

What is Visible-Light-Driven Synthesis of Aryl Xanthates and Aryl Dithiocarbamates via an Electron Donor–Acceptor Complex about?

Herein, we report a facile, efficient, and practical protocol that enables the preparation of aryl xanthates and aryl dithiocarbamates from functionalized dibenzothiophenium salts via a photoactivated electron donor-acceptor complex. This mild, metal-free method is operationally simple and has a broad substrate scope and potential utility for late-stage functionalization of natural products and pharmaceuticals. Finally, this method also has redefined the substrate scope and reaction pathway for the Leuckart thiophenol reaction.

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Author

Mingjun Zhang; Beibei Wang; Yunpeng Cao; Yuxiu Liu; Ziwen Wang; Qingmin Wang

Publisher

American Chemical Society (ACS)

Published

2022

Language

EN

Field

Chemistry (Physical Sciences)