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An electrochemical cell consists of two half-cells joined by a salt bridge, allowing ions to flow between the half-cells while electrons flow through an external wire. The half-cells contain different electrodes, such as inert, membrane, or metallic electrodes, and ions undergo oxidation or reduction reactions at the anode and cathode. The cell potential depends on the electrode reactions and can be used to determine if a redox reaction will occur spontaneously based on thermodynamic calculations.

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