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The document summarizes acid-catalyzed rearrangements of alcohols of the 6,14-endo-ethenotetrahydrothebaine series. Specifically: 1) The alcohols are dehydrated to olefins under acid. Some olefins further rearrange to 14-alkenylcodeinones. 2) The 14-alkenylcodeinones can undergo further rearrangements under more dilute acid to form recyclized products like 6-hydroxy derivatives or carbinol methyl ethers. 3) Catalytic reductions can yield 14-alkyldihydrocodeinones or 14-alkenylcodeines depending on cond

Author
Swoll Jones
Language
EN