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Can I read Asymmetric Cyclopropanation of Electron-rich Alkenes by the Racemic Diene Rhodium Catalyst: the Chiral Poisoning Approach on EtoBox?
Asymmetric Cyclopropanation of Electron-rich Alkenes by the Racemic Diene Rhodium Catalyst: the Chiral Poisoning Approach by Evgeniya A. Trifonova; Nikita M. Ankudinov; Denis A. Chusov; Yulia V. Nelyubina; Dmitry S. Perekalin is a Chemistry article available to read on EtoBox.
What is Asymmetric Cyclopropanation of Electron-rich Alkenes by the Racemic Diene Rhodium Catalyst: the Chiral Poisoning Approach about?
Asymmetric cyclopropanation of alkenes by aryldiazoacetates was achieved using the readily-available racemic (diene)rhodium complex in combination with the chiral oxazoline-phenol ligand, which acts as the chiral poison and selectively inhibits one of the enantiomers of the catalyst. This approach eliminates a common problematic step of the synthesis of chiral catalysts.
Who reads Asymmetric Cyclopropanation of Electron-rich Alkenes by the Racemic Diene Rhodium Catalyst: the Chiral Poisoning Approach?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Evgeniya A. Trifonova; Nikita M. Ankudinov; Denis A. Chusov; Yulia V. Nelyubina; Dmitry S. Perekalin
- Published
- 2022
- Language
- EN
- Field
- Chemistry (Physical Sciences)