Can I read Monocarbaborane Anion Chemistry: Use of an Anilinyl Residue as an Anchor Group for the Construction of Rod-like Monocarbaboranyl Diazo and Imino Compounds on EtoBox?

Monocarbaborane Anion Chemistry: Use of an Anilinyl Residue as an Anchor Group for the Construction of Rod-like Monocarbaboranyl Diazo and Imino Compounds by Andreas Franken; Colin A. Kilner; John D. Kennedy is a Materials Science article available to read on EtoBox.

What is Monocarbaborane Anion Chemistry: Use of an Anilinyl Residue as an Anchor Group for the Construction of Rod-like Monocarbaboranyl Diazo and Imino Compounds about?

Reaction of the [1-(4-H 2 N-C 6 H 4 )-closo-1-CB 9 H 9 ] À anion 1 with Me 2 CHCH 2 CH 2 ONO and dilute HCl gives neutral [1-(4-N 2 -C 6 H 4 )-closo-1-CB 9 H 9 ] 3, which reacts with PhNH 2 to form the 19.5 À azo anion 2. Anion 1 with ketones and aldehydes gives imino compounds: with (CH 3 ) 2 CO it gives neutral [1-{4-(Me 2 C@NH)-C 6 H 4 }closo-1-CB 9 H 9 ] 6 and with the para-dialdehyde C 6 H 4 -1,4-(CHO) 2 it gives the 30.5 A A extended rod-like neutral species [C 6 H 4 -1,4-{1-(CH@NH-C 6 H 4 )-closo-1-CB 9 H 9 } 2 ] 8.

Who reads Monocarbaborane Anion Chemistry: Use of an Anilinyl Residue as an Anchor Group for the Construction of Rod-like Monocarbaboranyl Diazo and Imino Compounds?

Author

Andreas Franken; Colin A. Kilner; John D. Kennedy

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 1387-7003)

Published

2003

Language

EN

Field

Materials Science (Physical Sciences)