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Synthesis of γ-Acoradiene (α-Alaskene) and δ-Acoradiene by John N. Marx; Lewis R. Norman is a Chemistry article available to read on EtoBox.
What is Synthesis of γ-Acoradiene (α-Alaskene) and δ-Acoradiene about?
We wish to report syntheses of y-acoradiene (IX) and &-acoradiene (X), two spirocyclic sesquiterpenes isolated from Juniperus rigida. 1 y-Acoradiene has been shown to be identical to a-alaskene, isolated from Alaska cedar, Chamaecyparis nootkatensis,' though S-acoradiene is enantiomeric to b-alaskene from the same source. ## 2. 3 Previous syntheses of members of the acorane class have been reported for racemic forms of an unnamed acoradiene' and for a compound which was an intermediate in a biogenetic-like synthesis of a-cedrene6 and which has the structure assigned later to a-acorenol. 1 Some other synthetic approaches toward acoranes have also been reported. ## 7-9 The synthesis of y-and 6-acoradiene is summarized in Chart I. R(+)-pulegone (I) was converted into 3-methyl-2-carbethoxycyclopentanone
Who reads Synthesis of γ-Acoradiene (α-Alaskene) and δ-Acoradiene?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- John N. Marx; Lewis R. Norman
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 1973
- Language
- EN
- Field
- Chemistry (Physical Sciences)