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This document describes a laboratory practice in which students prepared the coordination complex [Cu(DMSO)2Cl2] from CuCl2 and DMSO. Through IR spectroscopy, they determined that the DMSO ligand coordinates to copper through the oxygen instead of sulfur, since the S=O absorption band appeared at a frequency lower than 1050 cm-1. The objective was to recognize the behavior of the DMSO ligand in its ability to coordinate through either oxygen or sulfur.

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