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Millimeter- and submillimeter-wave spectroscopy of platinum monocyanide, PtCN by Emi Y. Okabayashi; Toshiaki Okabayashi; Takashi Furuya; Mitsutoshi Tanimoto is a Physics and Astronomy article available to read on EtoBox.

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Monomeric platinum cyanide, PtCN, was detected in the gas phase by employing a source-modulated microwave spectrometer. The PtCN radical was generated in a free space cell using the sputtering reaction from a platinum sheet placed on the inner surface of a stainless steel cathode through a dc glow plasma of CH 3 CN diluted with Ar. The rotational constants obtained for several isotopomers indicated that the monomeric platinum cyanide is in a cyanide form (PtCN) and not in an isocyanide form (PtNC). Observed fine-and hyperfine-spectral patterns suggest that the PtCN radical has the 2 D 5=2 electronic ground state.

Who reads Millimeter- and submillimeter-wave spectroscopy of platinum monocyanide, PtCN?

Author

Emi Y. Okabayashi; Toshiaki Okabayashi; Takashi Furuya; Mitsutoshi Tanimoto

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

2010

Language

EN

Field

Physics and Astronomy (Physical Sciences)