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Can I read Reactivity of π-pentadienyl complexes. Stereochemistry of the addition of amines to the (syn,syn-1,5-dimethylpentadienyl)iron tricarbonyl cation on EtoBox?
Reactivity of π-pentadienyl complexes. Stereochemistry of the addition of amines to the (syn,syn-1,5-dimethylpentadienyl)iron tricarbonyl cation by G. Maglio; A. Musco; R. Palumbo is a Chemistry article available to read on EtoBox.
What is Reactivity of π-pentadienyl complexes. Stereochemistry of the addition of amines to the (syn,syn-1,5-dimethylpentadienyl)iron tricarbonyl cation about?
Strongiy basic amines react with the (syqsyn-1,5-dimethylpentadienyI)iron tricarbonyl cation to give (c&runs-dienylamine)iron tricarbonyl complexes through an exo attack of the nucleophile on the coordinated pentadienyl group. Weakly basic amines give (trans,trans-dienylamine)iron tricarbonyl complexes, i.e., the reaction proceeds with geometrical inversion\_ The stereochemistry of the new complexes has been elucidated by NMR, CD and X-ray analysis. \* To whom correspondence should be addressed c/o ICM., Milano. \*\* The ~X&~QCIZ of ag eqtibtiu~~~ between tis-and mms-ptmtadimyliraa lricz.rhnyl ~Z~S&S b?s b recently demonstrated by low temperature NMR experiments'.
Who reads Reactivity of π-pentadienyl complexes. Stereochemistry of the addition of amines to the (syn,syn-1,5-dimethylpentadienyl)iron tricarbonyl cation?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- G. Maglio; A. Musco; R. Palumbo
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 1971
- Language
- EN
- Field
- Chemistry (Physical Sciences)