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Phase Behaviour and Molecular Dynamics in the Binary System of Sodium Perchlorate and 1,2-Propanediamine by Yukio Terashima; Kiyoshi Takeda; Makoto Honda is a Chemical Engineering article available to read on EtoBox.

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The phase and glass transition behaviour in a binary mixture of sodium perchlorate and 1,2-propanediamine {(NaClO 4 ) x (12PDA) 1Àx , x < 0.40} was investigated by differential scanning calorimetry and Raman scattering measurements. A eutectic point and a peritectic point were found at x = 0.17 and 0.19, respectively. The phase diagram indicates the existence of solvated compounds of (NaClO 4 ) 1 (12PDA) 4 and (NaClO 4 ) 2 (12PDA) 5 . The concentration dependence of the glass transition point shows a sigmoid curve implying an underlying anomaly.

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Author

Yukio Terashima; Kiyoshi Takeda; Makoto Honda

Publisher

Elsevier Science; Elsevier ; Elsevier Inc.; Elsevier BV (ISSN 0021-9614)

Published

2011

Language

EN

Field

Chemical Engineering (Physical Sciences)