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Can I read The Kinetic Modeling of Soot Precursors in a Butadiene Flame on EtoBox?
The Kinetic Modeling of Soot Precursors in a Butadiene Flame by A Goldaniga; T Faravelli; E Ranzi is a Engineering article available to read on EtoBox.
What is The Kinetic Modeling of Soot Precursors in a Butadiene Flame about?
A comprehensive, semidetailed kinetic scheme, describing hydrocarbon oxidation has been applied to the simulation of a premixed, rich, nearly sooting, butadiene, laminar flame. The main goal of this work was to understand the mechanism and to validate a general detailed kinetic model for the prediction of both polycyclic aromatic hydrocarbons (PAHs) and soot precursors from the pyrolysis and oxidation of butadiene. The modeling computations are in quite good agreement with the experimental measurements. Under these conditions, butadiene undergoes particular pathways involving resonantly stabilized radicals. Molecular reactions explain almost all the consumption of butadiene during its pyrolysis, while the additions on double bonds are of great importance in explaining the formation of the first aromatic rings, and, consequently, of PAHs. Kinetic analysis allows identification of the radical C 4 H 5 as being the major contributing factor in the initial formation of benzene and naphthalene. Several combustion byproducts and radicals are quite well simulated by the model, although important discrepancies in the prediction of CH 4 were found. To extend the validity of the developed sch
Who reads The Kinetic Modeling of Soot Precursors in a Butadiene Flame?
It is typically read by researchers, students, and practitioners in Engineering.
- Author
- A Goldaniga; T Faravelli; E Ranzi
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0010-2180)
- Published
- 2000
- Language
- EN
- Field
- Engineering (Physical Sciences)