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A Novel Cyclopropanol Formation by P.S. Venkataramani; William Reusch is a Chemistry article available to read on EtoBox.
What is A Novel Cyclopropanol Formation about?
Reduction of unsaturated functi'ons by alkali metal in liquid ammonia solutions is a widely used synthetic method, ly2 and the large body of data regarding these reactions is in substantial agreement with currently accepted mechanistic rationalisations.3 In this communication we report an unexpected transformation of the enedione I which represents a new diversion in enone reductions. Allylation of dihydroresorcinol followed by Michael addition of methyl vinyl ketone yielded a monocyclic triketone which was cyclized to I, mp 61.5-62.5, by the action of pyrrolidine. The structure of I was supported by its analysis, infrared spectrum (vmax 1705,
Who reads A Novel Cyclopropanol Formation?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- P.S. Venkataramani; William Reusch
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 1968
- Language
- EN
- Field
- Chemistry (Physical Sciences)