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Effect of Pincer Methylation On Cobalt Catalyzed CSP H Borylation by f20230821 is a document available to read on EtoBox.
This study explores the impact of methylation on PNP pincer cobalt complexes for C(sp²)–H borylation of fluoroarenes, revealing that while methylation enhances stability by preventing P–C bond cleavage, it simultaneously reduces catalytic activity and alters selectivity. The findings highlight a critical trade-off between stability and activity due to increased steric hindrance from methyl groups. Future ligand designs must balance rigidity for stability with flexibility for optimal catalytic performance.
- Author
- f20230821
- Language
- EN