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Catalytic Behavior of a Silica-supported Polystannazane-copper Complex for the Oxidation of Methanol to Formaldehyde at Mild Reaction Conditions by Li-Ming Tang; Qiang He; Mei-Yu Huang; Ying-Yang Jiang is a Materials Science article available to read on EtoBox.

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## Abstract A very cheap catalyst, a silica‐supported polystannazane‐copper complex (abbreviated as SiO~2~SnNCu) was prepared by the reaction of the silica‐supported polystannazane ligand with CuCl~2~ in ethanol. The results showed that SiO~2~SnNCu can catalyze the oxidation of methanol to formaldehyde in high yield at mild conditions, i.e. at 40°C and 1 atm of oxygen. The catalyst could be recovered and could catalyze the reaction repeatedly.

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Author

Li-Ming Tang; Qiang He; Mei-Yu Huang; Ying-Yang Jiang

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1022-1336)

Published

1995

Language

EN

Field

Materials Science (Physical Sciences)