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The phenyl α- and β-L-idopyranosiduronic acids and some other aryl glycopyranosiduronic acids by Robert B. Friedman; Bernard Weissmann is a Biochemistry, Genetics and Molecular Biology article available to read on EtoBox.
What is The phenyl α- and β-L-idopyranosiduronic acids and some other aryl glycopyranosiduronic acids about?
Condensation of 1,2,3,4,6-penta-0-acetyl-a-L-ldopyranose (I) with phenol yrelded phenyl 2,3,4,6-tetra-O-acetyl-a-(2) and B-r\_-ldopyranoslde (4) Deacetylatlon of 2 and 4 afforded phenyl a-and P-L-ldopyranosldes (3 and 5), respectively, the structures of which were vertied by penodate oxldatlon studxes A platinum-catalyzed oxtdatton of 3 and 5 produced the amorphous phenyl OL-and /3-L-ldopyranostdurontc acids (9 and ll), respectively, which were Isolated as the crystallme cyclohexylammomum salts Phenyl /3-and a-D-glucopyranoslduromc acids are apparent mmor byproducts of the catalytic oxldatlons, resulting from an inversIon at C-5 p-Nltrophenyl U-D-mannopyranoslduromc acid and p-mtrophenyl LX-and P-D-galactopyranoslduromc acrds are also described
Who reads The phenyl α- and β-L-idopyranosiduronic acids and some other aryl glycopyranosiduronic acids?
It is typically read by researchers, students, and practitioners in Biochemistry, Genetics and Molecular Biology.
- Author
- Robert B. Friedman; Bernard Weissmann
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0008-6215)
- Published
- 1972
- Language
- EN
- Field
- Biochemistry, Genetics and Molecular Biology (Life Sciences)