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What is Synthesis of Ledgerquinone from Cinchona about?
The synthesis of the natural product ledgerquinone is described. In the first route, benzyne 3 was generated and trapped with the anion 8 to yield ledgerquinone (1) in 26% yield. A second route utilizing monobromide 5 provided a slightly higher yield of 33%. The structure of synthetic ledgerquinone matched the reported natural product. Both routes provide simple syntheses of this natural anthraquinone.
- Author
- darsonmanullang
- Language
- EN