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Novel Characterization of the Crystalline Segment Distribution and Its Effect on the Crystallization of Branched Polyethylene by Differential Scanning Calorimetry by Hongxiang Teng; Yi Shi; Xigao Jin is a Materials Science article available to read on EtoBox.
What is Novel Characterization of the Crystalline Segment Distribution and Its Effect on the Crystallization of Branched Polyethylene by Differential Scanning Calorimetry about?
## Abstract Based on a thermal segregation treatment, a novel semiquantitative method for the characterization of the crystalline segment distribution in branched polyethylene copolymers was established by the results of differential scanning calorimetry being treated with the Gibbs–Thomson equation. The method was used to describe the segment distribution of Ziegler–Natta‐catalyzed linear low‐density polyethylene (Z–N LLDPE), metallocene‐catalyzed linear low‐density polyethylene (m‐LLDPE), and a commercial linear low‐density polyethylene with a wide molecular weight distribution. The isothermal crystallization kinetics of Z–N LLDPE and m‐LLDPE were studied to assess the effect of different segment distributions. According to their molecular characteristics, the crystallization behaviors were analyzed. They indicated that the different segment distributions of the two polymers resulted in different crystallization processes, including the nucleation and growth of crystals under various crystallization conditions. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2107–2118, 2002
Who reads Novel Characterization of the Crystalline Segment Distribution and Its Effect on the Crystallization of Branched Polyethylene by Differential Scanning Calorimetry?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Hongxiang Teng; Yi Shi; Xigao Jin
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-6266)
- Published
- 2002
- Language
- EN
- Field
- Materials Science (Physical Sciences)