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Efficient Production of Valuable Aromatic N-Heterocycles from Bio-Polyols by Heterogeneous Catalysis via Controlling Unstable Intermediate Conversion by Yu, Feng (author);Xiao, Feng-Shou (author) is a Engineering article available to read on EtoBox.

What is Efficient Production of Valuable Aromatic N-Heterocycles from Bio-Polyols by Heterogeneous Catalysis via Controlling Unstable Intermediate Conversion about?

Efficient and controllable conversion of renewable polyols to valuable N-containing products by heterogeneous catalysis, especially under relativley mild conditions ( 98 C%) level. More importantly, organic solvent-enabled kinetics control of competitive reactions associated with PA transformation, i.e., the condensation with aryl-1,2-diamine to produce 2-MQs and the Cannizzaro reaction to form lactic acid, allowed to access the desired 2-MQs in a controllable manner with yields ranging from 12 C% to 81 C%. The application of this approach to attain diverse 2-MQs and analogues of interest in pharmaceutical industry has been demonstrated.

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Author

Yu, Feng (author);Xiao, Feng-Shou (author)

Publisher

American Chemical Society (ACS)

Published

2023

Language

EN

Field

Engineering (Physical Sciences)