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Interlayer structure of iodide intercalated layered double hydroxides (LDHs) by S.V. Prasanna; P. Vishnu Kamath; C. Shivakumara is a Chemistry article available to read on EtoBox.

What is Interlayer structure of iodide intercalated layered double hydroxides (LDHs) about?

The iodide-containing layered double hydroxides (LDHs) of Mg and Zn with Al crystallize by the inclusion of extensive positional disorder of I À ions in the interlayer region. I À ion given its poor charge to size ratio can neither screen effectively the positive charge nor participate in H-bonding with the metal hydroxide layers. Thereby the I À ions are not stabilized in sites close to the seat of positive charge of the metal hydroxide layers (6c), nor in sites that facilitate H-bonding (3b or 18h). On the other hand, OH À from water can do both and effectively displaces I À from the interlayer.

Who reads Interlayer structure of iodide intercalated layered double hydroxides (LDHs)?

Author

S.V. Prasanna; P. Vishnu Kamath; C. Shivakumara

Publisher

Elsevier Science; Elsevier ; Elsevier Inc.; Elsevier BV (ISSN 0021-9797)

Published

2010

Language

EN

Field

Chemistry (Physical Sciences)