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Single site electronic spectroscopy of palladium chlorin in n-octane matrixes at 7K by Amarnauth Singh; Wen-Ying Huang; Peter Scheiner; Lawrence W. Johnson is a Chemistry article available to read on EtoBox.

What is Single site electronic spectroscopy of palladium chlorin in n-octane matrixes at 7K about?

The high resolution, single site emission and absorption spectra of palladium chlorin (PdC) in n-octane matrixes at 7 K are reported. The emission and Q and Soret band absorption regions were investigated. The vibrational frequencies of the ground and the lowest energy \* excited states were determined from luminescence and excitation spectra, respectively. The emission from PdC was entirely phosphorescence. The emission and Q y region spectra of the complex are similar, having intense, narrow origin bands followed by relatively weak but orderly vibrational structure. The Q x region of this metal chlorin does not have a clear origin and exhibits complex vibrational structure which increases in intensity going to higher energy. In the Soret region of PdC there is only a single intense, broad band.

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Author
Amarnauth Singh; Wen-Ying Huang; Peter Scheiner; Lawrence W. Johnson
Publisher
Elsevier Science; Elsevier ; Elsevier Ltd.; Pergamon Press Ltd.; Elsevier BV (ISSN 1386-1425)
Published
2007
Language
EN
Field
Chemistry (Physical Sciences)

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