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Effect of delithiation on the dimer transition of the honeycomb-lattice ruthenate Li$ {2-x}$RuO$ 3$ by Jimenez-Segura, Marco-Polo; Ikeda, Atsutoshi; Kimber, Simon A. J.; Giacobbe, Carlotta; Yonezawa, Shingo; Maeno, Yoshiteru is a scholarly article available to read on EtoBox.

What is Effect of delithiation on the dimer transition of the honeycomb-lattice ruthenate Li$ {2-x}$RuO$ 3$ about?

The honeycomb-lattice ruthenate Li$_2$RuO$_3$ is made heavily Li-deficient by chemical oxidation by iodine. The delithiation triggers a different phase Li$_{2-x}$RuO$_3$, the "D-phase", with superlattice. For the first time we disclose the magnetic and structural properties of the D-phase in the dimer-solid state. The low temperature magnetic susceptibility and the bond lengths indicate a bonding configuration consisting of both Ru$^{4+}$-Ru$^{4+}$ and Ru$^{5+}$-Ru$^{5+}$ dimers.

Author

Jimenez-Segura, Marco-Polo; Ikeda, Atsutoshi; Kimber, Simon A. J.; Giacobbe, Carlotta; Yonezawa, Shingo; Maeno, Yoshiteru

Published

2016

Language

EN