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Crystal and molecular structures of two triorganophosphinegold(I) 2-amino-cyclopent-1-ene-1-carbodithioates by Soo Yei Ho; Edward R. T. Tiekink is a Chemistry article available to read on EtoBox.

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## Abstract The molecular structures of Ph~3~PAu · (S~2~CC~5~H~6~NH~2~-2) and (4-MeOC~6~H~4~)~3~PAu(S~2~CC~5~H~6~NH~2~-2) · CH~2~Cl~2~ display the expected linear S-Au-P coordination geometries. The hydrogen-bonding functionality in the 1,1-dithiolate ligands, __i.e__., —NH~2~ groups, allows for the formation of hydrogen-bonded, __i.e__., N—H...S, mediated chains in the respective crystal structures.

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Author
Soo Yei Ho; Edward R. T. Tiekink
Publisher
Walter de Gruyter GmbH
Published
2004
Language
EN
Field
Chemistry (Physical Sciences)

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