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Selection of Species in Divalent Rhodium Hexacyanide Using Pulsed EPR by J.A. Coelho Neto; N.V. Vugman is a Chemistry article available to read on EtoBox.

What is Selection of Species in Divalent Rhodium Hexacyanide Using Pulsed EPR about?

The superposition of paramagnetic species in CW EPR spectra SELECTION OF SPECIES usually prevents the measurement of spectral parameters. Separation of superimposed species can be performed in field-swept In the EPR spectra of [Rh(CN) 6 ] 40 paramagnetic species pulsed EPR by choosing a convenient pulse sequence in such a created by radiation damage in K 3 [Rh(CN) 6 ] in KCl host way that species with different relaxation times can be distinctly lattice, the poorly resolved perpendicular spectra seems to affected. Computer subtraction between spectra taken under difbe a seven-line multiplet, leading to the reported g ⊥ and A ⊥ ferent conditions may lead to better species identification. For T 2measurements (1). Through CW Q-band power variation based selection, the difference between FID-detected and long t measurements, Fig. 1, there was observed an intensity variaecho-detected spectra is used. This technique is successfully aption of the rightmost lines relative to the others in the multiplied to the [Rh(CN) 6 ] 40 paramagnetic species created by radiation plet, pointing to the existence of superimposed spectra from damage in [Rh(CN) 6 ] 30 in a KCl host lattice, where spectra co

Who reads Selection of Species in Divalent Rhodium Hexacyanide Using Pulsed EPR?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
J.A. Coelho Neto; N.V. Vugman
Publisher
Elsevier Science; Elsevier ; Elsevier Inc.; Elsevier BV (ISSN 1090-7807)
Published
1997
Language
EN
Field
Chemistry (Physical Sciences)

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