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Direct Determination of Glyphosate Using Hydrophilic Interaction Chromatography with Coulometric Detection at Copper Microelectrode by Cláudia F.B. Coutinho; Lincoln F.M. Coutinho; Luiz H. Mazo; Suzana L. Nixdorf; Carlos A.P. Camara; Fernando M. Lanças is a Chemistry article available to read on EtoBox.
What is Direct Determination of Glyphosate Using Hydrophilic Interaction Chromatography with Coulometric Detection at Copper Microelectrode about?
A simple, rapid, and low-cost coulometric method for direct detection of glyphosate using hydrophilic interaction chromatography is presented. The principle of detection is based on the enhancement of the anodic current of copper microelectrode in the presence of complexing agents, such as glyphosate, with the formation of a soluble Cu(II) complex. Under optimized conditions, the limit of detection (S/R=3) for glyphosate was 0.1 mg L(-1) (0.59 microM) without any preconcentration method. The calibration curve has been found linear in all concentration range tested (from limit of detection to 34 mg L(-1)) with an excellent correlation coefficient (0.9999). The present method was successfully applied for the determination of glyphosate in fruit juices without any kind of extraction, clean-up, or preconcentration step, with recoveries of 92 and 90% for apple and grape juice, respectively.
Who reads Direct Determination of Glyphosate Using Hydrophilic Interaction Chromatography with Coulometric Detection at Copper Microelectrode?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Cláudia F.B. Coutinho; Lincoln F.M. Coutinho; Luiz H. Mazo; Suzana L. Nixdorf; Carlos A.P. Camara; Fernando M. Lanças
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0003-2670)
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)