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An enhanced anaerobic digestion BioModel calibrated by parameters optimization based on measured biogas plant data 1 1 Introduction 1 2 Biogas plant operation data 5 3 Mathematical formulation of the proposed ad model 5 3.1 Biochemical and physicochemical reactions 6 3.1.1 Biochemical reactions 7 3.1.2 Physicochemical reactions 9 3.2 CSTR performance equations 9 3.2.1 Liquid phase 9 3.2.2 Liquid-gas phase transition 12 3.2.3 Liquid-solid phase transition 12 3.2.4 Gas phase 14 3.2.5 Solid phase 14 4 Calibration of AD model parameters 14 4.1 Active set optimization procedure 14 4.2 Optimization problem 16 4.3 Evaluation methodology 20 5 Results and discussion 20 5.1 Model calibration 21 5.2 Model validation 21 6 Conclusions 22 CRediT authorship contribution statement 22 Declaration of Competing Interest 22 Acknowledgements 22 Appendix A Acknowledgements 22 Appendix B Acknowledgements 23 Appendix C Acknowledgements 26 References 26

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nonfiction