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Decoupling Oxygen and Chlorine Evolution Reactions in Seawater using Iridium‐based Electrocatalysts by Jesse S. Ko; James K. Johnson; Phillip I. Johnson; Zhiyong Xia is a Chemistry article available to read on EtoBox.

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A series of iridium (Ir) organometallic-based electrocatalysts fused onto high surface-area activated carbon using pyrolysis were prepared for the oxygen evolution reaction (OER) in seawater electrolysis. These catalysts had a low loading of Ir (< 6 wt%), while also inducing atom coordination to the Ir center. The morphology and chemical composition of these electrocatalysts were analyzed by scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy, which all showed a uniform dispersion of Ir and heteroatom-doped moieties. To assess electrocatalytic activity, we used an artificial electrolyte comprising 0.1 M HClO4 + 3.5 wt% NaCl, and found that these catalysts delivered a low overpotential of 243 mV, a low Tafel slope (92 mV dec -1 ), and a high exchange current density (1.40 mA cm -2 ). By using a headspace chlorine gas (Cl2) detector in situ, we discovered that a Cl2 content of 27 ppm was present. When tested in synthetic Atlantic seawater, the overpotential exhibited a two-fold increase, yet Cl2 was undetected, thus indicating favorable OER kinetics. This significant finding exemplifies the need for in situ Cl2 detection for seawat

Who reads Decoupling Oxygen and Chlorine Evolution Reactions in Seawater using Iridium‐based Electrocatalysts?

Author

Jesse S. Ko; James K. Johnson; Phillip I. Johnson; Zhiyong Xia

Publisher

Wiley

Published

2020

Language

EN

Field

Chemistry (Physical Sciences)