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Selectivity-enhancement in enantioselective hydrolysis of sec-alkyl sulfates by an alkylsulfatase from Rhodococcus ruber DSM 44541 by Mateja Pogorevc; Ulrike T. Strauss; Thomas Riermeier; Kurt Faber is a Chemistry article available to read on EtoBox.

What is Selectivity-enhancement in enantioselective hydrolysis of sec-alkyl sulfates by an alkylsulfatase from Rhodococcus ruber DSM 44541 about?

The Enantioselectivity of the biohydrolysis of sec-alkyl sulfate esters using a bacterial alkylsulfatase from Rhodococcus ruber DSM 44541 was dramatically enhanced in presence of additives ('enhancers') such as carbohydrates, polyethylene glycol, detergents, metal ions and through enzyme immobilization. In presence of iron, the E value for the kinetic resolution of (±)-3-and (±)-4-octyl sulfate was improved from E=3.9 to ]200 and E=1.1 to 10, respectively.

Who reads Selectivity-enhancement in enantioselective hydrolysis of sec-alkyl sulfates by an alkylsulfatase from Rhodococcus ruber DSM 44541?

Author

Mateja Pogorevc; Ulrike T. Strauss; Thomas Riermeier; Kurt Faber

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0957-4166)

Published

2002

Language

EN

Field

Chemistry (Physical Sciences)