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Reactions of Diheteroaryl Sulfoxides with Heteroaryllithiums—ligand Coupling and Exchange Reactions by Yoichi Inubushi; Masakuni Yoshihara; Shigeru Oae is a Chemistry article available to read on EtoBox.

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The reactions of heteroaryl sulfoxides with heteroaryllithiums gave various biheteroaryls and diheteroaryl sulfoxides as ligand coupling and ligand exchange products through sulfurane intermediates. Especially, the reaction of di-2-fury1 sulfoxide with 2-pyridyllithium proceeded first by a ligand exchange reaction to form 2-furyllithium and 2-fury1 2-pyridyl sulfoxide, which then underwent ligand coupling with 2-pyridyllithium to afford 2,2'-bipyridyl. Furthermore, it was found that the occurrence of the ligand coupling reaction depends on the stereoisomerism of the sulfurane intermediate formed.

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Author

Yoichi Inubushi; Masakuni Yoshihara; Shigeru Oae

Publisher

John Wiley and Sons; Hindawi Limited; John Wiley & Sons Inc.; Wiley (ISSN 1042-7163)

Published

1996

Language

EN

Field

Chemistry (Physical Sciences)