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Structure and Rheology of Oil-continuous Capillary Suspensions Containing Water-swellable Cellulose Beads and Fibres by Philipp L. Fuhrmann; Jeffrey Powell; Dérick Rousseau is a Agricultural and Biological Sciences article available to read on EtoBox.

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Cellulose particles are used in a range of materials and applications. Here, we investigated the role of cellulose sorptivity on the rheology and microstructure of oil-continuous capillary suspensions consisting of cellulose beads and fibres at volume fractions of 0.3–0.65 and water at volume fractions up to 0.2. We hypothesised that, in spite of their water-absorbent nature, cellulose particles in oil would be structured into a percolated network by water added as an immiscible secondary phase. The interplay between cellulose bead load and water content was used to generate suspensions ranging from flowable to highly elastic with moduli near 1 MPa. While capillary bridging induced a liquid to semi-solid transition, nearer particle volume fractions of 0.65, we found a transition to a solid, wet-granular material. Liquid-solid transitions occurred even if the water was absorbed by the particles, suggesting that the increase in elasticity was not solely due to the formation of capillary bridges, but also as a result of clustering and the associated increase in effective packing volume fraction. Swapping the beads with fibres increased stiffness by 4 orders whereas swapping half of th

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Author

Philipp L. Fuhrmann; Jeffrey Powell; Dérick Rousseau

Publisher

Elsevier BV

Published

2023

Language

EN

Field

Agricultural and Biological Sciences (Life Sciences)