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Can I read Enzymatic Synthesis of Enantiomerically Enriched D- and L-3-silylated Alanines by Deracemization of Dl-5-silylmethylated Hydantoins on EtoBox?
Enzymatic Synthesis of Enantiomerically Enriched D- and L-3-silylated Alanines by Deracemization of Dl-5-silylmethylated Hydantoins by Richard J. Smith; Markus Pietzsch; Thomas Waniek; Christoph Syldatk; Stefan Bienz is a Chemistry article available to read on EtoBox.
What is Enzymatic Synthesis of Enantiomerically Enriched D- and L-3-silylated Alanines by Deracemization of Dl-5-silylmethylated Hydantoins about?
The hydantoinase process was shown to be extendable to the production of highly lipophilic, silicon-containing amino acids. Two hydantoinases of different origin and stereoselectivities and one L-N -carbamoylase were used for the highly stereoselective bioconversion of (dimethyl)phenylsilyl-and 1-methyl-1-silacyclopentyl substituted alanine derivatives. The enantiomeric purities and absolute configuration of the products were determined with reference compounds that were synthesized with the aid of the Evans oxazolidinone auxiliary.
Who reads Enzymatic Synthesis of Enantiomerically Enriched D- and L-3-silylated Alanines by Deracemization of Dl-5-silylmethylated Hydantoins?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Richard J. Smith; Markus Pietzsch; Thomas Waniek; Christoph Syldatk; Stefan Bienz
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0957-4166)
- Published
- 2001
- Language
- EN
- Field
- Chemistry (Physical Sciences)