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SYLLABUS- B.Sc. CHEMISTRY-II, INORGANIC CHEMISTRY-II1.Chemical BondingMolecular Orbital Theory (MOT) as applied to diatomic homonuclear/heteronuclear inorganic molecules. MOdiagrams and bond order of H2, He2, Li2, Be2, B2, C2, N2, O2, F2, Ne2, CO and NO, difference between VB andMO theories. Multicentre bonding in electron deficient molecules. Polarization of covalent molecules;percentage ionic character from dipole and electronegativity difference. Weak interactions-hydrogen bondingand Van der Waals forces.2.Ionic SolidsIonic structures, radius-ratio effects and coordination number. Lattice defects, semiconductors, lattice energyand Borne-Haber cycle. Solvation energy and solubility of ionic solids. Polarizing power and polarizability;Fajan's rule. Metallic bond- Electron Pool and MO theories.3.s-Block ElementsGeneral discussion with respect to all periodic and chemical properties, diagonal relationship, salient features ofhydrides, solvation and complexation tendencies, an introduction to their alkyls and aryls. Role of alkali andalkaline earth metal ions in bio-systems.4.p-Block ElementsGeneral discussion and comparative study (all periodic and chemical properties) including dia

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Online2PDF.com

Published

2021

Language

EN